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Chemistry · States & structure

States of matter

CIE 06202 min read

Solids, liquids and gases

SolidsLiquidsGases
Fixed shapeTakes shape of containerNo fixed shape
Fixed volumeFixed volumeNo fixed volume
Cannot flowCan flowCan flow
Cannot compressHard to compressCan compress
Arranged so particles are tightly packed in latticeArranged so particles are touchingFree, spread out particles
Particles vibrate in placeParticles slide over each otherMove around quickly and randomly

Changes of state

  • Melting — Solid -> Liquid
  • Boiling — Liquid -> Gas
  • Evaporating — Liquid -> Gas
  • Condensing — Gas -> Liquid
  • Freezing — Liquid -> Solid

Evaporation vs boiling

EvaporationBoiling
Surface levelHappens throughout liquid
Does not happen at a fixed temperatureHappens at a fixed temperature (boiling point)
Bubbles not producedBubbles produced
Remaining liquid is cooledRemaining liquid boils at one temp

Kinetic particle theory

When a substance is changing it can either:

  1. Gain kinetic energy from heat, which causes the particles to vibrate more vigorously. They then gain enough energy to break free of their bonds. E.g. Liquid -> Gas
  2. Lose energy to their surroundings. The particles move closer to each other, moving less vigorously. E.g. Gas -> Liquid

Factors affecting changing states

  • Temperature — Increases kinetic energy of particles, particles move more rapidly.
  • Pressure — Pushes particles closer to each other. Can change the state of matter if decreased or increased sufficiently (e.g. if a gas is under very high pressures, the particles can be pushed together so densely that a liquid is formed.)

Cooling curve

Heating curve


Diffusion

The net movement of particles from an area of high concentration to an area of low concentration down a concentration gradient as a result of random particle movement.

Factors affecting the rate of diffusion

  1. Relative molecular mass — The heavier the molecular mass, the slower the diffusion.
  2. Temperature — The higher the temperature, the faster the diffusion, as particles have more energy and move quicker.

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